《材料化学》(第2版)与其获得美国教材与作者协会(Text and Academic Authors Association, TAA)颁发的2008年度最佳教科书奖的第1版相比,内容有所加强。
第2版从结构-特性处理的角度出发,探讨了无机、有机、纳米材料等课题,在广度和深度上基本涵盖了当今飞速发展的材料科学领域。
第2版自始至终为读者继续呈现突破创新和实际应用的视角。在扼要地定义材料化学和其发展史之后,全书7章逐一讨论了固态化学、金属、半导体材料、有机“软”材料、纳米材料和材料的性能等内容。
第2版得到了全新的升级和扩展.例如,新增加“软平版印刷术”模型、“点击化学”聚合反应、纳米毒 性、石墨烯以及许多生物材料应用等内容,特别是聚合物和“软”材料部分得到了更大的补充。
每一章直至每一节都详细地描述了重要材料的实际应用,辅以精选的问题耐人寻味。
附录同样精彩——不但提供了最新的材料合成实验室方法,而且列举了比较重要的材料的发现时间表。
样章试读
目录
- Contents
Preface ix
Chapter l.WHAT IS MATERIALS CHEMISTRY? 1
1.1 HISTORICAL PERSPECTIVES 2
1.2 CONSIDERATIONSIN THE DESIGN OF NEW MATERIALS 5
1.3 DESIGN OF NEW MATERIALS THROUGH A “CRITICAL THINKING” APPROACH 6
Chapter 2.SOLID-STATE CHEMISTRY 13
2.1 AMORPHOUS VS CRYSTALLINE SOLIDS 13
2.2.3 Covalent Network Solids 18
2.3.3 Crystal Symmetry and Space Groups 56
2.3.4 X-Ray Diffraction from Crystalline Solids 65
2.3.6 Physical Properties of Crystals 88
2.3.7 Bonding in Crystalline Solids: Introduction to Band Theory 103
2.4 THE AMORPHOUS STATE 113
2.4.1 Sol-Gel Pr ocessing 114
2.4.2 Glasses 125
2.4.3 Cementitious Materials 136
2.4.4 Ceramics 139
Chapter 3.METALS 157
3.1 MIBfING AND PROCESSING OF METALS 157
3.1.1 Powder Metallurgy 171
3.2 METALLIC STRUCTURES AND PROPERTIES 177
3.2.1 Phase Behavior oflron-Carbon Alloys 178
3.2.2 Hardening Mechanisms ofSteels 185
3.2.4 Nonferrous Metals and Alloys 204
3.3 METAL SURFACE TREATMENTS FOR CORROS10N RES1STANCE 217
3.4 MAGNETISM 220
3.5 REVERSIBLE HYDROGEN STORAGE 226
Chapter 4.SEMICONDUCTORS 239
4.1 PROPERTIES AND TYPES OF SEMICONDUCTORS 239
4.2 SILICON-BASED APPLICATIONS 251
4.3 LIGHT-EMITTING DIODES: THERE IS LIFE OUTSIDE OF S1LICON! 321
4.4 THERMOELECTRIC (TE) MATERIALS 330
Chapter 5.POLYMERIC MATERIALS 349
5.1 POLYMER CLASSIFICATIONS AND NOMENCLATURE 351
5.2 POLYMERIZATION MECHANISMS 356
5.2.4 Step-GrowthPolymerization 372
5.2.6 Polymerization via “Click” Chemistry 386
5.3 “SOFT MATERIALS” APPLICATIONS:STRUCTURE VS PROPERTIES 388
5.3.1BiomaterialsApplications 393
5.4.1 Flame Retardants 440
Chapter 6.NANOMATERIALS 457
6.1 NANOTOXICITY 458
6.2 WHA T IS “NANOTECHNOLOGY”? 468
6.3 NANOSCALE BUILDING BLOCKS AND APPLICATIONS 470
6.3.1 Zero-DimensionalNan伪naterials 473
6.3.2 0ne-DimensionalNanostructures 529
6.3.3 Two-DimensionalNanostructures:The “Graphene Frontier” 559
Chapter 7.MATERIALS CHARACTERIZ.ATION 585
7.1 OPTICAL MICROSCOPY 586
7.2 ELECTRON MICROSCOPY 588
7.2.1 Electron Sources 593
7.2.2 Transmission Electron Microscopy (TEM) 597
7.2.3 Scanning Electron Microscopy (SEM) 617
7.3 SURFACECHARACTERIZATIONTECHNIQUES BASED ON PARTICLE BOMBARDMENT 629
7.3.1 Photoelectron Spectroscopy (PES) 629
7.3.2 X-ray Absorption Fine Structure (XAFS) 631
7.3.3 Ion-BombardmentTechniques 634
7.3.4 Atom-Probe Tomography (APT) 643
7.4 SCANNING PROBE MICROSCOPY (SPM) 645
7.5 BULK CHARACTERIZATION TECHNIQUES 651
APPENDIX A 669
APPENDIX B 681
APPENDIX C 693
C.l CHEMICAL VAPOR DEPOSITION OF CARBON NANOTUBES 693
C.l.l Backgroundlnformation 693
C.1.2 Procedure 695
C.2 SUPERCRITICAL FLUID FACILITATED GROWTH OF COPPER AND ALUMINUM OXIDE NANOPARTICLES 697
C.2.1 Procedure 698
C.3 SYNTHESIS AND CHARACTERIZATION OF LIQUID CRYST ALS 700
C.3.1 Procedure 703
C.4 TEMPLATE SYNTHESIS AND MAGNETIC MANIPULATION OF NICKEL NANOWIRES 705
C.4.1 Procedure 705
C.5 INTRODUCTION TO PHOTOLITHOGRAPHY 709
C.5.1 Procedure 709
C.6 SYNTHESIS OF GOLD NANOCLUSTERS 712
C.6.1 Procedure 712
C.7 SYNTHESIS OF POROUS SILICON 713
C.7.1 Procedure 714
C.8 SOLID-LIQUID-SOLID (SLS) GROWTH OF SILICON NANOWIRES 714
C.8.1 Procedure 716
C.9 SYNTHESIS OF FERROFLUIDS 717
C.10 METALLURGY/PHASE TRANSFORMATIONS 717
C.ll HEAT TREATMENT OF GLASS CERAMICS 717
Index 719